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- W2102658766 abstract "The present study focuses on the terpolymer of styrene (St), isoprene (Ip), and butadiene (Bd) synthesized together in cyclohexane at 70°C with neodymium (Nd) compound, alkylaluminum, and chlorinating agent (Cl) rare earth cocatalyst system. The resultants possessed atactic St–St sequences and high cis-1,4 polyconjugated olefins in macromolecular chains besides controllable composition. The composition of the St–Ip–Bd terpolymers and molecular weight (Mw), molecular weight distribution (Mw/Mn) were controlled through the adjustment of Nd compound, alkylalumium, monomers feed ratio (St/Ip/Bd), and [Nd]/[monomers]. With the inventory rating of St raised from 15% to 55%, the content of St in the terpolymers got increased from 2% to 15%. And the content of the Ip segments and Bd segments in the terpolymers increased from 33% to 56% and from 28% to 54%, respectively, with the proportion of Ip/Bd varied from 1/2 to 2/1. As the [Nd]/[monomers] varied from 1.0 × 10−3 to 5.0 × 10−4, the molecular weight increased from 1.3 × 104 to 2.7 × 104. According to the proton nuclear magnetic resonance (1H-NMR) and 13C-NMR, it was proved that both microstructures of polybutadiene segments and polyisoprene segments were high cis-1,4-configuration. A single glass-transition temperature was observed in the differential scanning calorimetry curve. POLYM. ENG. SCI., 54:1858–1863, 2014. © 2013 Society of Plastics Engineers" @default.
- W2102658766 created "2016-06-24" @default.
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- W2102658766 date "2013-08-24" @default.
- W2102658766 modified "2023-09-27" @default.
- W2102658766 title "The terpolymer of neodymium-catalyzed styrene, isoprene, and butadiene: Efficient synthesis of integral rubber containing atactic styrene-styrene sequences and high Cis-1,4 polyconjugated olefins" @default.
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- W2102658766 doi "https://doi.org/10.1002/pen.23731" @default.
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