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- W2102878499 abstract "A base-promoted reaction between alkyl 2-aroyl-1-chlorocyclopropanecarboxylates and acylhydrazones is described. In common solvents, the reactions proceed smoothly under mild conditions, providing mainly the formal substitution product , as well as a little amount of the formal [3 + 2] cycloaddition product . This strained bicyclic pyrazolidine , however, became the predominant product in DMSO. Moreover, a novel aromatization process of the fused pyrazolidine into 2,3,5-trisubstituted pyrrole has been successfully achieved in excellent yield via treatment with a HCl-pyridine system." @default.
- W2102878499 created "2016-06-24" @default.
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- W2102878499 date "2015-01-01" @default.
- W2102878499 modified "2023-10-18" @default.
- W2102878499 title "Formation and aromatization of strained bicyclic pyrazolidines via tandem reaction of alkyl 2-aroyl-1-chlorocyclopropanecarboxylates with acylhydrazones" @default.
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- W2102878499 doi "https://doi.org/10.1039/c5ob01199j" @default.
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