Matches in SemOpenAlex for { <https://semopenalex.org/work/W2102885644> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W2102885644 endingPage "2088" @default.
- W2102885644 startingPage "2077" @default.
- W2102885644 abstract "A novel polyaddition of p-benzenedithiol (BDT) to p-diethynylbenzene (DEB) was studied in solid state under UV or γ-ray irradiation at 25–99°C. Thin layer crystals of the 1:1 mixture of BDT and DEB mounted on a glass plate were prepared by a sublimation of an equimolar amount of the mixture of BDT and DEB at 45–80°C under a reduced pressure of nitrogen. The thin layer crystal of the 1:1 mixture of BDT and DEB and that of polymers exhibited almost similar and high crystalline diffraction patterns on x-ray diagraph. Consequently, the polyaddition in the solid state was a topotactic reaction controlled by the crystal lattice of the 1:1 mixture of BDT and DEB. The arrangement of both compounds in the thin layer crystal of the 1:1 mixture of BDT and DEB is seemingly quite ordered induced by a molecular interaction between BDT and DEB, and this is supported on the basis of the broad absorption at 340–450 nm by the diffuse reflectance spectrum taken with the thin layer crystal of the 1:1 mixture of BDT and DEB. The melting point of the 1:1 mixture of BDT and DEB was 90–94°C. However, the polyaddition at 87°C proceeded in a molten state perhaps due to heat evolved in the polyaddition. In the solid state polyaddition Mn of polymers obtained was 3–4 × 103, whereas in the molten state polyaddition the crystallinity of polymers remarkably decreased, and Mn increased several times." @default.
- W2102885644 created "2016-06-24" @default.
- W2102885644 creator A5040031208 @default.
- W2102885644 creator A5056682256 @default.
- W2102885644 creator A5062512480 @default.
- W2102885644 date "1987-08-01" @default.
- W2102885644 modified "2023-09-26" @default.
- W2102885644 title "Polyaddition of p-benzenedithiol to p-diethynylbenzene in solid state under UV irradiation" @default.
- W2102885644 doi "https://doi.org/10.1002/pola.1987.080250805" @default.
- W2102885644 hasPublicationYear "1987" @default.
- W2102885644 type Work @default.
- W2102885644 sameAs 2102885644 @default.
- W2102885644 citedByCount "17" @default.
- W2102885644 countsByYear W21028856442020 @default.
- W2102885644 crossrefType "journal-article" @default.
- W2102885644 hasAuthorship W2102885644A5040031208 @default.
- W2102885644 hasAuthorship W2102885644A5056682256 @default.
- W2102885644 hasAuthorship W2102885644A5062512480 @default.
- W2102885644 hasConcept C107814960 @default.
- W2102885644 hasConcept C111337013 @default.
- W2102885644 hasConcept C113196181 @default.
- W2102885644 hasConcept C121332964 @default.
- W2102885644 hasConcept C13530604 @default.
- W2102885644 hasConcept C147789679 @default.
- W2102885644 hasConcept C15744967 @default.
- W2102885644 hasConcept C171250308 @default.
- W2102885644 hasConcept C178790620 @default.
- W2102885644 hasConcept C185544564 @default.
- W2102885644 hasConcept C185592680 @default.
- W2102885644 hasConcept C188027245 @default.
- W2102885644 hasConcept C19067145 @default.
- W2102885644 hasConcept C192562407 @default.
- W2102885644 hasConcept C199360897 @default.
- W2102885644 hasConcept C2781285689 @default.
- W2102885644 hasConcept C41008148 @default.
- W2102885644 hasConcept C46275449 @default.
- W2102885644 hasConcept C521977710 @default.
- W2102885644 hasConcept C542102704 @default.
- W2102885644 hasConcept C58437636 @default.
- W2102885644 hasConcept C8010536 @default.
- W2102885644 hasConceptScore W2102885644C107814960 @default.
- W2102885644 hasConceptScore W2102885644C111337013 @default.
- W2102885644 hasConceptScore W2102885644C113196181 @default.
- W2102885644 hasConceptScore W2102885644C121332964 @default.
- W2102885644 hasConceptScore W2102885644C13530604 @default.
- W2102885644 hasConceptScore W2102885644C147789679 @default.
- W2102885644 hasConceptScore W2102885644C15744967 @default.
- W2102885644 hasConceptScore W2102885644C171250308 @default.
- W2102885644 hasConceptScore W2102885644C178790620 @default.
- W2102885644 hasConceptScore W2102885644C185544564 @default.
- W2102885644 hasConceptScore W2102885644C185592680 @default.
- W2102885644 hasConceptScore W2102885644C188027245 @default.
- W2102885644 hasConceptScore W2102885644C19067145 @default.
- W2102885644 hasConceptScore W2102885644C192562407 @default.
- W2102885644 hasConceptScore W2102885644C199360897 @default.
- W2102885644 hasConceptScore W2102885644C2781285689 @default.
- W2102885644 hasConceptScore W2102885644C41008148 @default.
- W2102885644 hasConceptScore W2102885644C46275449 @default.
- W2102885644 hasConceptScore W2102885644C521977710 @default.
- W2102885644 hasConceptScore W2102885644C542102704 @default.
- W2102885644 hasConceptScore W2102885644C58437636 @default.
- W2102885644 hasConceptScore W2102885644C8010536 @default.
- W2102885644 hasIssue "8" @default.
- W2102885644 hasLocation W21028856441 @default.
- W2102885644 hasOpenAccess W2102885644 @default.
- W2102885644 hasPrimaryLocation W21028856441 @default.
- W2102885644 hasRelatedWork W1964247085 @default.
- W2102885644 hasRelatedWork W1979804573 @default.
- W2102885644 hasRelatedWork W2025894896 @default.
- W2102885644 hasRelatedWork W2090471961 @default.
- W2102885644 hasRelatedWork W2138783486 @default.
- W2102885644 hasRelatedWork W2391692263 @default.
- W2102885644 hasRelatedWork W2412535117 @default.
- W2102885644 hasRelatedWork W2899084033 @default.
- W2102885644 hasRelatedWork W3023101005 @default.
- W2102885644 hasRelatedWork W316412761 @default.
- W2102885644 hasVolume "25" @default.
- W2102885644 isParatext "false" @default.
- W2102885644 isRetracted "false" @default.
- W2102885644 magId "2102885644" @default.
- W2102885644 workType "article" @default.