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- W2102896751 abstract "Abstract A diethyl tartrate linked chiral macrocyclic manganese(III)–salen (salen= N , N ′‐ethylenebis(salicylimine)) complex has been used for the enantioselective epoxidation of nonfunctionalized alkenes, namely, indene and chromenes, as well as oxidative kinetic resolution of racemic alcohols. For the epoxidation reaction, a 2.5 mol % catalyst loading in the presence of pyridine N ‐oxide as an axial ligand and urea–H 2 O 2 adduct as an oxidant gave respective epoxides in high yield (>97 %) and enantiomeric excess ( ee , up to 92 %). The same catalyst at a loading of 1.5 mol % has provided enantioenriched ( ee up to 97 %) secondary alcohols through oxidative kinetic resolution of racemic alcohols. The catalyst can be recovered and reused up to four times with no loss in performance." @default.
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- W2102896751 date "2014-06-30" @default.
- W2102896751 modified "2023-10-18" @default.
- W2102896751 title "Diethyl Tartrate Linked Chiral Macrocyclic Manganese(III)-Salen Complex for Enantioselective Epoxidation of Olefins and Oxidative Kinetic Resolution of Racemic Secondary Alcohols" @default.
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- W2102896751 doi "https://doi.org/10.1002/cplu.201402131" @default.
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