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- W2102966084 endingPage "2132" @default.
- W2102966084 startingPage "2123" @default.
- W2102966084 abstract "A highly effective and facile synthesis route is developed to create and tailor metal-decorated and nitrogen-functionalized active microporous carbon materials from ZIF-8. Clear metal- and pyrrolic-N-induced enhancements of the cyclic CO2 uptake capacities and binding energies are achieved, particularly at a much lower carbonization temperature of 700 °C than those often reported (1000 °C). The high-temperature carbonization can enhance the porosity but only at the expense of considerable losses of sample yield and metal and N functional sites. The findings are comparatively discussed with carbons derived from metal-organic frameworks (MOFs) reported previously. Furthermore, the porosity of the MOF-derived carbon is critically dependent on the structure of the precursor MOF and the crystal growth. The current strategy offers a new and effective route for the creation and tuning of highly active and functionalized carbon structures in high yields and with low energy consumption." @default.
- W2102966084 created "2016-06-24" @default.
- W2102966084 creator A5057814917 @default.
- W2102966084 creator A5069576290 @default.
- W2102966084 date "2015-04-27" @default.
- W2102966084 modified "2023-10-16" @default.
- W2102966084 title "Tuning of ZIF-Derived Carbon with High Activity, Nitrogen Functionality, and Yield - A Case for Superior CO<sub>2</sub>Capture" @default.
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