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- W2103011337 abstract "The kinetics of oxidation of diethylamine and triethylamine by [RuV=O(EDTA)]− were studied spectrophotometrically as a function of [RuV=O(EDTA)]− and [amine] at a fixed pH of 5.0 and ionic strength of 0.2 M NaClO4. The reaction rate was followed by observing the disappearance of the characteristic peak at 393 nm of the oxo complex RuV=O(EDTA)− with time. Oxidative N-dealkylation of tertiary and secondary amines produces secondary and primary amines respectively as oxidation products, the N-alkyl group being oxidized to the corresponding aldehyde. The oxidation reactions were studied at three different temperatures and activation parameters (ΔH‡ and ΔS‡) calculated. A mechanism involving a hydride shift from the α-carbon of the substrate to the oxo oxygen is proposed for the oxidation of amines by RuV=O(EDTA)−. The experimental results are discussed with reference to the oxidation of the corresponding amines with molecular oxygen catalysed by the [RuIII(EDTA)(H2O)]− complex." @default.
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- W2103011337 date "1991-08-01" @default.
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- W2103011337 title "Kinetics and mechanism of oxidation of diethylamine and triethylamine by [RuV=O(EDTA)]− in aqueous medium" @default.
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- W2103011337 doi "https://doi.org/10.1016/0304-5102(91)80043-3" @default.
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