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- W2103045707 abstract "Complexes trans-[FeHL(dppe)2][BF4] (II: L CNR; R Me, But, C6H4OMe-4 or C6H4NO2-4. III: L N2; dppe Ph2PCH2CH2PPh′2) have been obtained from the reaction of trans-[FeHCl(dppe)2] (I) with the appropriate ligand L in the presence of TlBF4. In cyclic voltammetry, at a sufficiently low scan rate, compound II (R Me) undergoes an anodic ECE process, with metalhydride bond rupture (proton loss) and metal fluorination, to give trans-[FeF(CNMe)(dppe)2][BF4], which has been electrosynthesized by CPE." @default.
- W2103045707 created "2016-06-24" @default.
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- W2103045707 date "1987-10-01" @default.
- W2103045707 modified "2023-09-27" @default.
- W2103045707 title "Electrochemical metalhydride bond cleavage at the dinitrogen-binding iron centre {FeH(Ph2PCH2CH2PPh2)2}+, and its electroactivation towards nucleophilic attack" @default.
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- W2103045707 doi "https://doi.org/10.1016/0022-328x(87)85107-0" @default.
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