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- W2103077369 abstract "The adhesion behavior of semi-interpenetrating polymer networks (semi-IPNs) of linear polystyrene (PS) in crosslinked poly-2-ethylhexylmethacrylate (EHMA) was studied by variation of the bulk and surface morphology, i.e., domain size, continuity, and concentration in the domains. Semi-IPNs were prepared by liquid-liquid demixing upon cooling of a homogeneous solution of PS in methacrylate monomer, followed by gelation of the PS-rich phase and UV polymerization of the methacrylate resin. Welding of films allowed the preparation of larger objects provided that (1) the samples were phase separated to a high degree and contained domains with a high PS concentration (>90%) and (2) polystyrene was present at the interface. For semi-IPN films, a linear dependence of the adhesion strength on the (crack healing time)1/4 was obtained. Based on these considerations, a process was developed to obtain melt-processable semi-IPN particles, by quenching droplets of the polymer solution into a cold liquid. These particles obtained a PS-rich skin layer and showed good adhesion after blending with a thermoplast. © 1996 John Wiley & Sons, Inc." @default.
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- W2103077369 date "1996-08-01" @default.
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- W2103077369 title "Influence of the bulk and surface morphology on adhesion of polystyrene-inter-poly-cross-2-ethylhexyl-methacrylate films and particles" @default.
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- W2103077369 doi "https://doi.org/10.1002/(sici)1099-0488(199608)34:11<1839::aid-polb1>3.0.co;2-n" @default.
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