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- W2103111189 abstract "We describe a blue/green inorganic material, Ba3(P1 − x Mn x O4)2 (I) based on tetrahedral MnO $_{4}^{3-}$ :3d 2chromophore. The solid solutions (I) which are sky-blue and turquoise-blue for x ≤ 0·25 and dark green for x ≥ 0·50, are readily synthesized in air from commonly available starting materials, stabilizing the MnO $_{4}^{3-}$ chromophore in an isostructural phosphate host. We suggest that the covalency/ionicity of P–O/Mn–O bonds in the solid solutions tunes the crystal field strength around Mn(V) such that a blue colour results for materials with small values of x. The material could serve as a nontoxic blue/green inorganic pigment." @default.
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- W2103111189 date "2011-10-01" @default.
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- W2103111189 title "Ba3(P1 − x Mn x O4)2 : Blue/green inorganic materials based on tetrahedral Mn(V)" @default.
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- W2103111189 doi "https://doi.org/10.1007/s12034-011-0164-7" @default.
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