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- W2103136460 abstract "E. M. F. of the Cell, Cd-Hg (2-phase)/CdAc2(m), Hg2Ac2(s)/Hg was measured at 20°, 25°, 30° and 40°C. The standard e. m. f. of the cell, Cd/CdAc3(m), Hg2Ac2(c)/Hg was evaluated as E°=1.1500−11.09×10−4T+1.06×10−8T2 The thermodynamic data of the reaction, Cd(c) + Hg2Ac2(c)=2Hg(l)+Cd++(aq)+2Ac−(aq) at 25°C were estimated as ΔF°=−42,139, ΔH°=−48,698 cal mole−1 and ΔS°=−22.0 cal deg−1 mole−1 at 25°C. The thermodynamic data for the formation of Hg2Ac2(s) were evaluated as ΔFf°=−202.3, ΔHf°=−154.5 Kcal mole−1 and S°=72.9 cal deg−1 mole−1. From measurements of the heats of solution of CdAc2·2H2O in aqueous solution, the relative partial molal enthalpies of cadmium acetate in aqueous solution were estimated." @default.
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- W2103136460 date "1969-12-01" @default.
- W2103136460 modified "2023-10-16" @default.
- W2103136460 title "Thermodynamic Studies of Bi-Univalent Electrolytes. VI. Thermodynamics of Cadmium Acetate from E. M. F. and Calorimetric Measurements" @default.
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- W2103136460 doi "https://doi.org/10.1002/jccs.196900016" @default.
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