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- W2103146117 abstract "The reaction between allene and hydrogen over unsupported nickel, iron, and cobalt catalysts has been studied in a static constant volume system for a wide range of temperature and reactant ratios. The reaction over metals is largely simple hydrogenation, the early stages being principally a selective formation of propylene with small yields of reduced polymers of allene. The orders of the hydrogenation were 1 and 0 with respect to hydrogen and allene respectively, and were temperature independent. The overall apparent activation energies for nickel, iron, and cobalt were 6.5, 7.6, and 6.9 kcal/mole respectively. Selectivity was highest with nickel, and least with cobalt." @default.
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- W2103146117 date "1968-10-15" @default.
- W2103146117 modified "2023-09-26" @default.
- W2103146117 title "The hydrogenation of allene. II. The reaction of allene with hydrogen catalyzed by nickel, cobalt, and iron" @default.
- W2103146117 doi "https://doi.org/10.1139/v68-538" @default.
- W2103146117 hasPublicationYear "1968" @default.
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