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• W2103148928 abstract "Graphene, carbon in the form of monolayer sheets, has revealed astonishing and unique chemical and physical properties, which have made it an extremely active research topic in both materials science and physics (Novoselov, K. S. et al., 2004). Through chemical and materials integration, graphene is being actively exploited in a range of technological applications (Stankovich, S. et al., 2006). Superconductors can carry electrical current without any energy dissipation. The combination of both graphene and a superconductor into a composite has great potential for electrical devices and large scale applications. MgB2, a superconductor with a simple composition and two-gap feature has great potential for large current carrying applications, as demonstrated through a series of chemical dopings (Dou, S. X. et al. 2007). In the case of graphene’s, the strict two-dimensionality and its high electrical and thermal conductivities, make it an ideal candidate for integrating/doping into MgB2 in order to improve the superconducting properties. Substitutional chemistry can modify, in a controlled way, the electronic structures of superconductors and their superconducting properties, such as the transition temperature (Tc), critical current density (Jc), upper critical field (Hc2), and irreversibility field (Hirr). In particular, carbon containing dopants, including nano-meter sized carbon (nano-C), silicon carbide (SiC), carbon nanotubes (CNTs) and hydrocarbons/carbohydrates are effective means to enhance the Jcfield dependence and Hc2 (Ma, Y. et al., 2006, Senlowocz, B. J. et al., 2005, Kumakura, H. et al., 2004, Sumption, M. et al., 2005, Dou, S. X. et al., 2003, Kim, J. H. et al., 2006, Wilke, R. H. T. et al., 2008). Upon graphene incorporation into MgB2 it is expected that Hc2 and the flux pinning properties should be improved. Recently, high-throughput solution processing of large-scale graphene has been reported by a number of groups (Tung, V. C. et al., 2009, Kim, K. S. et al., 2009, Hernandez, Y. et al., 2008, Li, D. et al., 2008, Li, X. et al., 2008, Choucair, M. et al., 2009). Based on the works of Choucair et al., sufficient quantities of graphene were obtained for doping the bulk MgB2 samples via a diffusion process. it was demonstrate that graphene is the most efficient among all the carbon-based dopants used to date, in terms of enhancing the flux pinning behaviour in MgB2. Very low levels of graphene doping (e,g. 0.9 at%) have been shown to be sufficient to lead to a significant improvement in the critical current density field performance (Jc(B)), with little change in the transition temperature (Tc). At 3.7 at% graphene doping of MgB2 an optimal enhancement in Jc(B) was reached by a factor of 30 at 5 K and 10 T, compared to the un-doped reference" @default.
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• W2103148928 date "2011-06-27" @default.
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• W2103148928 title "Superconducting Properties of Graphene Doped Magnesium Diboride" @default.
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• W2103148928 doi "https://doi.org/10.5772/17117" @default.
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