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• W2103157466 abstract "The mass resolution of a time-of-flight (TOF) mass spectrometer is directly proportional to its total flight pathlength. Multi-turn or multi-passage ion optical geometries are necessary to obtain fight distances of sufficient length within reasonable size limitations. We have investigated ion optics for a multi-turn TOF mass spectrometer with electrostatic sectors. The concept of 'perfect' focusing conditions is introduced. Furthermore, a new type of multi-turn TOF mass spectrometer, the MULTUM Linear plus, was developed. It consists of four cylindrical electric sectors and 28 electric quadrupole lenses. It has a vacuum chamber 60 x 70 x 20 cm in size. Mass resolution is demonstrated to increase according to the number of ion cycles. A mass resolution of 350 000 (m/z = 28, FWHM) was achieved after 501.5 cycles. The MULTUM Linear plus analyzer is not simple, however; 28 electric quadrupole lenses are used. In order to reduce the number of ion optical parts, an improved multi-turn TOF mass spectrometer, the MULTUM II, consisting of only four toroidal electric sectors, was also developed. The possibility of tandem mass spectrometric applications using multi-turn TOF mass spectrometers is also discussed." @default.
• W2103157466 created "2016-06-24" @default.
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• W2103157466 date "2003-11-01" @default.
• W2103157466 modified "2023-10-10" @default.
• W2103157466 title "Multi-turn time-of-flight mass spectrometers with electrostatic sectors" @default.
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• W2103157466 doi "https://doi.org/10.1002/jms.546" @default.
• W2103157466 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14648820" @default.
• W2103157466 hasPublicationYear "2003" @default.
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