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• W2103163888 abstract "NH group makes all the difference: The highly stereoselective nitro-Mannich reaction of α-substituted nitroacetates and N-Boc aldimines was investigated catalyzed by novel chiral bifunctional thiourea/secondary-amine systems (an example is shown here). The presence of a basic NH group is crucial for the stereocontrol. The products with adjacent quaternary and tertiary chiral centers were directed isolated in moderate to good yields for an array of substrates (91–96 % ee). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2111/2008/z801170_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
• W2103163888 created "2016-06-24" @default.
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• W2103163888 date "2008-09-15" @default.
• W2103163888 modified "2023-10-18" @default.
• W2103163888 title "Discovery of Bifunctional Thiourea/Secondary-Amine Organocatalysts for the Highly Stereoselective Nitro-Mannich Reaction of α-Substituted Nitroacetates" @default.
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• W2103163888 doi "https://doi.org/10.1002/chem.200801170" @default.
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