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- W2103168006 abstract "Photochemical reactions of camphor and other diones with carbonylmanganese or aryltin compounds lead to paramagnetic complexes. The radicals derived from Mn2(CO)10 and Mn2(CO)8(PR3)2 are formulated as sixcoordinate complexes with different structures depending on the organic moiety, and they are characterized by their EPR and ENDOR data. Under the same conditions, the tin compounds form five-coordinate complexes in which the organic ligand occupies one equatorial and one axial position in the bipyramidal structure. Consequently, two permutation isomers are expected if camphor quinone is used as a scavenger for the photolytically generated tin radicals, independent of the structure of the trapped species. These two species can be detected by ENDOR and triple resonance experiments if the interconversion is slow with respect to the EPR time scale. Diastereomeric complexes are obtained by the formation of a second chiral centre, at the tin atom, in the course of the reaction. However, these isomers cannot be distinguished by ENDOR spectroscopy under the conditions applied." @default.
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- W2103168006 date "1992-09-01" @default.
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- W2103168006 title "Organometallic paramagnetic camphor complexes. EPR investigation of their formation and structures" @default.
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