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- W2103183629 abstract "Interaction between HKrCl and N2 is investigated in a low temperature Kr matrix and by using ab initio calculations. Two configurations of the HKrCl⋯N2 complex are found both computationally and experimentally. The complexes show large monomer-to-complex blueshifts (+112.9 and +32.4 cm−1 experimentally) of the H–Kr stretching vibration mode. The large blueshifts are attributed to the enhanced (HKr)+Cl− ion-pair character of complexed HKrCl resulting in stronger H–Kr covalent bonding." @default.
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- W2103183629 date "2002-07-03" @default.
- W2103183629 modified "2023-10-11" @default.
- W2103183629 title "Large blueshift of the H–Kr stretching frequency of HKrCl upon complexation with N2" @default.
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- W2103183629 doi "https://doi.org/10.1063/1.1491403" @default.
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