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• W2103188633 endingPage "2853" @default.
• W2103188633 startingPage "2845" @default.
• W2103188633 abstract "Abstract The total synthesis of the bacterial‐derived, pentacyclic, antitumor antibiotic lavendamycin has been achieved through a highly convergent strategy. The key step of this synthesis is a ruthenium‐catalyzed [2+2+2] cycloaddition of an electron‐deficient nitrile to an alkynyl‐ynamide to prepare the carboline scaffold. The elaborate cycloaddition substrate is obtained in few steps by an N ‐ethynylation using alkynyliodonium salt chemistry and two palladium‐catalyzed cross‐coupling reactions. An efficient synthesis of a halogenated quinoline‐5,8‐dione building block starting from hydroquinone is presented." @default.
• W2103188633 created "2016-06-24" @default.
• W2103188633 creator A5056741004 @default.
• W2103188633 creator A5079650886 @default.
• W2103188633 date "2011-04-05" @default.
• W2103188633 modified "2023-10-18" @default.
• W2103188633 title "Total Synthesis of Lavendamycin by a [2+2+2] Cycloaddition" @default.
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• W2103188633 doi "https://doi.org/10.1002/ejoc.201100131" @default.
• W2103188633 hasPublicationYear "2011" @default.
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