Matches in SemOpenAlex for { <https://semopenalex.org/work/W2103192043> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W2103192043 abstract "Trialkylsilyl groups play an important role as effective protecting groups in organic synthesis. Various O, N, and C nucleophilic sites can be protected by trialkylsilyl groups to control the selectivity of reactions. The nucleophilic attack of a fluoride anion on a silyl group is recognized as one of the most useful methods for desilylation. The activation of the nucleophile–silicon bond is important not only for desilylation but also for the generation of a reactive nucleophilic anion to achieve a new bond formation. The phosphazene bases developed by Schwesinger are known to be strong non-metallic organic bases. Among them, the tBu-P4 base has been used for various selective deprotonative transformations, although the ability of tBu-P4 base to activate silylated nucleophiles has not yet been shown. A novel catalytic activation of various O, N, and C nucleophile–silicon bonds using tBu-P4 base was investigated to perform nucleophilic reactions with various electrophiles. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)" @default.
- W2103192043 created "2016-06-24" @default.
- W2103192043 creator A5001244440 @default.
- W2103192043 creator A5033311659 @default.
- W2103192043 creator A5050120621 @default.
- W2103192043 creator A5059739039 @default.
- W2103192043 creator A5067589689 @default.
- W2103192043 date "2005-09-27" @default.
- W2103192043 modified "2023-09-24" @default.
- W2103192043 title "Catalytic Activation of Silylated Nucleophiles Using tBu-P4 as a Base." @default.
- W2103192043 cites W2951604647 @default.
- W2103192043 doi "https://doi.org/10.1002/chin.200539038" @default.
- W2103192043 hasPublicationYear "2005" @default.
- W2103192043 type Work @default.
- W2103192043 sameAs 2103192043 @default.
- W2103192043 citedByCount "0" @default.
- W2103192043 crossrefType "journal-article" @default.
- W2103192043 hasAuthorship W2103192043A5001244440 @default.
- W2103192043 hasAuthorship W2103192043A5033311659 @default.
- W2103192043 hasAuthorship W2103192043A5050120621 @default.
- W2103192043 hasAuthorship W2103192043A5059739039 @default.
- W2103192043 hasAuthorship W2103192043A5067589689 @default.
- W2103192043 hasConcept C118792377 @default.
- W2103192043 hasConcept C134306372 @default.
- W2103192043 hasConcept C155647269 @default.
- W2103192043 hasConcept C161790260 @default.
- W2103192043 hasConcept C178790620 @default.
- W2103192043 hasConcept C178907741 @default.
- W2103192043 hasConcept C179104552 @default.
- W2103192043 hasConcept C185592680 @default.
- W2103192043 hasConcept C21951064 @default.
- W2103192043 hasConcept C2779019844 @default.
- W2103192043 hasConcept C2780828025 @default.
- W2103192043 hasConcept C33923547 @default.
- W2103192043 hasConcept C42058472 @default.
- W2103192043 hasConcept C50027330 @default.
- W2103192043 hasConcept C521977710 @default.
- W2103192043 hasConcept C5304478 @default.
- W2103192043 hasConceptScore W2103192043C118792377 @default.
- W2103192043 hasConceptScore W2103192043C134306372 @default.
- W2103192043 hasConceptScore W2103192043C155647269 @default.
- W2103192043 hasConceptScore W2103192043C161790260 @default.
- W2103192043 hasConceptScore W2103192043C178790620 @default.
- W2103192043 hasConceptScore W2103192043C178907741 @default.
- W2103192043 hasConceptScore W2103192043C179104552 @default.
- W2103192043 hasConceptScore W2103192043C185592680 @default.
- W2103192043 hasConceptScore W2103192043C21951064 @default.
- W2103192043 hasConceptScore W2103192043C2779019844 @default.
- W2103192043 hasConceptScore W2103192043C2780828025 @default.
- W2103192043 hasConceptScore W2103192043C33923547 @default.
- W2103192043 hasConceptScore W2103192043C42058472 @default.
- W2103192043 hasConceptScore W2103192043C50027330 @default.
- W2103192043 hasConceptScore W2103192043C521977710 @default.
- W2103192043 hasConceptScore W2103192043C5304478 @default.
- W2103192043 hasLocation W21031920431 @default.
- W2103192043 hasOpenAccess W2103192043 @default.
- W2103192043 hasPrimaryLocation W21031920431 @default.
- W2103192043 hasRelatedWork W2040662214 @default.
- W2103192043 hasRelatedWork W2099674531 @default.
- W2103192043 hasRelatedWork W2147427301 @default.
- W2103192043 hasRelatedWork W2336424505 @default.
- W2103192043 hasRelatedWork W2602259583 @default.
- W2103192043 hasRelatedWork W2951635445 @default.
- W2103192043 hasRelatedWork W2952520430 @default.
- W2103192043 hasRelatedWork W2997403453 @default.
- W2103192043 hasRelatedWork W4235938140 @default.
- W2103192043 hasRelatedWork W4238639654 @default.
- W2103192043 isParatext "false" @default.
- W2103192043 isRetracted "false" @default.
- W2103192043 magId "2103192043" @default.
- W2103192043 workType "article" @default.