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- W2103199095 abstract "A summary is presented of the mechanistic study of the 1 : 1 Kharasch addition reaction of polyhalogenated alkanes to olefins catalyzed by mononuclear or dendrimer-bound aryl-Ni complexes. These compounds contain the terdentate monoanionic aryldiamino ligand, [C6H2(CH2NMe2)2-2,6-R-4]- or (NCN). The catalysis occurs via inner sphere single electron transfer (SET) with the formation of a NiIII organometallic radical and a polyhalogenated alkane radical. This study is also relevant to the use of such compounds for the controlled radical polymerization of alkenes. A review is also given of the chemistry of α-diimine containing organozinc radicals that are also formed by a SET process. These metal-based radicals are useful for a variety of highly selective group transfer reactions in organic synthesis." @default.
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- W2103199095 date "1998-01-08" @default.
- W2103199095 modified "2023-10-16" @default.
- W2103199095 title "Selective Product Formation with Organometallic Radicals of Nickel and Zinc" @default.
- W2103199095 doi "https://doi.org/10.1021/bk-1998-0685.ch005" @default.
- W2103199095 hasPublicationYear "1998" @default.
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