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• W2103229942 startingPage "10434" @default.
• W2103229942 abstract "A nickel catalyst promotes the multicomponent coupling reaction of diketene, an alkyne, and Me2Zn to provide 3-methylene-4-hexenoic acids in excellent yields. Under similar conditions, the combination of the nickel catalyst and Et2Al(OEt) promotes a cycloaddition reaction involving dimerization of an alkyne to furnish phenylacetic acids. In the presence of PPh3, a formal [2+2+1+1] cycloaddition reaction proceeds to afford regioisomeric phenylacetic acids via cleavage of the CC bond." @default.
• W2103229942 created "2016-06-24" @default.
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• W2103229942 date "2014-08-05" @default.
• W2103229942 modified "2023-10-18" @default.
• W2103229942 title "Efficient and Selective Formation of Unsaturated Carboxylic and Phenylacetic Acids from Diketene" @default.
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• W2103229942 doi "https://doi.org/10.1002/anie.201404816" @default.
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