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- W2103257304 abstract "Die katalytische Ringöffnungspolymerisation von Cyclohepten 2 folgt der Umwandlung von 3 , in das entsprechende Metallacyclobutan. 3 , das in situ durch Addition von 2 an den Carbenkomplex 1 hergestellt und durch Tieftemperatur 1 H‐ und ‐ l3 C‐NMR‐Spektroskopie charakterisiert werden konnte, ist somit als echtes Schlüsselintermediat bei derartigen, auch technisch sehr bedeutsamen Reaktionen zu betrachten. Komplexe dieses Typs wurden bisher bei katalytischen Olefin‐Metathesen lediglich postuliert. R = CH 2 CMe 3 . magnified image" @default.
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- W2103257304 date "1992-12-01" @default.
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- W2103257304 title "Nachweis der Carben-Olefin-Intermediate in Metathese-Katalysatoren mit Wolfram in hoher Oxidationsstufe" @default.
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- W2103257304 doi "https://doi.org/10.1002/ange.19921041227" @default.
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