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- W2103261647 endingPage "4188" @default.
- W2103261647 startingPage "4188" @default.
- W2103261647 abstract "Two 3D coordination polymers of MnII with azide and bifunctional zwitterionic ligands bearing both carboxylate and tetrazolate groups, 1-(carboxylatomethyl)-3-(5-tetrazolato)pyridinium (L1) and 1-(carboxylatoethyl)-4-(5-tetrazolato)pyridinium (L2), were synthesized, and structurally and magnetically characterized. They are formulated as [Mn3(L1)2(N3)4(H2O)2]n·4nH2O (1) and [Mn3(L2)2(N3)4(H2O)3]n·3.5nH2O (2). In both compounds, octahedral MnII ions are linked by the mixed (μ2-EO-N3)(μ2-syn,syn-COO)(μ2-N2,N3-CN4) (CN4 = tetrazolate and EO = end-on) triple bridges to give anionic linear trinuclear motifs. The motifs are connected through EE-N3 (EE = end-to-end) bridges to give layers and chains in 1 and 2, respectively, and the cationic pyridinium spacers serve to interlink the layers or chains into three-dimensional frameworks with the α-Po and CdSO4-type topology, respectively. Magnetic studies demonstrated that the magnetic interactions within and between the trinuclear motifs, through the tricomponent and EE-N3 bridges, respectively, are both antiferromagnetic in both compounds." @default.
- W2103261647 created "2016-06-24" @default.
- W2103261647 creator A5026766436 @default.
- W2103261647 creator A5033884917 @default.
- W2103261647 creator A5044168602 @default.
- W2103261647 creator A5057298404 @default.
- W2103261647 creator A5084686610 @default.
- W2103261647 date "2012-01-01" @default.
- W2103261647 modified "2023-09-27" @default.
- W2103261647 title "Three-dimensional networks based on trinuclear motifs with tricomponent azide-carboxylate-tetrazolate cobridges: synthesis, structure and magnetic properties" @default.
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