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- W2103276089 abstract "Three crystalline layered metal (IV) acid phosphates α-M(DPO4)2·D2O, α-MP, (M= Zr, Ti, Pb) have been hydrothermally synthesized and the size and shape of the microparticles have been analyzed by the Scherrer method. The crystal structures of α-ZrP and α-TiP have been refined from a combined X-ray and neutron powder diffraction study by the Rietveld method. These hydrogen phosphates are isomorphous and belong to the α-ZrP-type structure. However, this precise powder diffraction study has shown that the frameworks and hydrogen-bond networks of these materials are slightly different. The unit cell volume of α-ZrP is larger than that of α-TiP because the layers in α-ZrP are less corrugated than those in α-TiP. The H-bond network is also slightly different, as in α-ZrP there is not H bonding between the layers, the shortest contact being O(7) ··· D(4) of 2.56(3) Å. For α-TiP this contact is much shorter, 2.33(2) Å, which may indicate a small but not negligible H-bond interaction between layers. Moreover, the intralayer H bonds are weaker in α-ZrP than in α-TiP as evidenced in the O(4) ··· D(3) interactions of 2.41(3) and 2.16(2) Å, respectively." @default.
- W2103276089 created "2016-06-24" @default.
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- W2103276089 date "1996-09-01" @default.
- W2103276089 modified "2023-09-30" @default.
- W2103276089 title "Structural Features of the Reactives Sites in α-M(DPO4)2·D2O(M= Ti, Zr, Pb): Hydrogen-Bond Network and Framework" @default.
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- W2103276089 doi "https://doi.org/10.1006/jssc.1996.0295" @default.
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