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- W2103290847 abstract "The ruthenium(II) dihydro complexes RuH2(CO)2(PnBu3)2, RuH2(CO)2(PPh3)2, and RuH2(PPh3)4 are able to hydrogenate/hydrogenolyse organic substrates containing single or multiple C–N bonds. The influence of several reaction parameters such as reaction time, temperature, hydrogen pressure and concentration of the catalyst were tested. A benzonitrile conversion of 76.5% was achieved after 24 h at 393 K. In the same conditions, N-benzylidenaniline is hydrogenated with a 92.1% conversion. Finally the activation parameters and the kinetic constants of these reactions were calculated. New ruthenium hydrido complexes containing a benzonitrile or an imine ligand were identified and spectroscopically characterized. A catalytic cycle was proposed to rationalize the results obtained, on the basis of the new complexes identified. To cite this article: A. Toti et al., C. R. Chimie 7 (2004)." @default.
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- W2103290847 date "2004-08-01" @default.
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- W2103290847 title "Activation of single and multiple C–N bonds by Ru(II) catalysts in homogeneous phase" @default.
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- W2103290847 doi "https://doi.org/10.1016/j.crci.2004.01.012" @default.
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