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• W2103303909 abstract "The ability of inorganic cyanometallate polymers to form interesting and useful complexes is well-known. This Account summarizes work, especially in our laboratories, aimed at replicating aspects of this inorganic chemistry in homogeneous solution using organometallic building blocks. A library of molecular organometallic cyanides and Lewis acids, with varying charges and labilities, are shown to give families of neutral and charged cages. Neutral and anionic cages, often molecular boxes, bind larger alkali metals tightly. Cubic frameworks show an unparalleled affinity for cesium cations over potassium cations. Noncubic cages are described including tetrahedranes, defect boxes, trigonal prisms, and hexagonal prisms." @default.
• W2103303909 created "2016-06-24" @default.
• W2103303909 creator A5005070123 @default.
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• W2103303909 date "2007-02-07" @default.
• W2103303909 modified "2023-10-03" @default.
• W2103303909 title "Evolution of Organo-Cyanometallate Cages: Supramolecular Architectures and New Cs⁺-Specific Receptors" @default.
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• W2103303909 doi "https://doi.org/10.1021/ar050215j" @default.
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• W2103303909 hasPublicationYear "2007" @default.
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