Matches in SemOpenAlex for { <https://semopenalex.org/work/W2103308453> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2103308453 endingPage "2242" @default.
- W2103308453 startingPage "2233" @default.
- W2103308453 abstract "A new, convenient, and safe route to 1,3,5-triamino-1,3,5-trideoxy-cis-inositol (taci) was investigated by hydrogenation of azo-coupled derivatives of phloroglucinol. In the presence of acetic anhydride, the reduction of trisphenylazophloroglucinol (H2/Pd(5%) on C) resulted in the formation of tri-, hexa-, and nona-acetylated derivatives of triaminophloroglucinol. All three compounds are air-stable, colorless solids. However, the succeeding hydrogenation to the cyclohexane derivative failed. Trisodiumtris(p-sulfonatophenylazo)phloroglucinol could be hydrogenated in a one-pot reaction to the desired taci· 1.5H2SO4 using a Pt/Rh oxide as catalyst. taci provides two distinct chair conformations with either three amino or three hydroxy groups for metal binding. The unique metal-binding properties are discussed in terms of minimal conformational changes required for coordination. Conformational analysis, based on X-ray structural data of [BiCl6][H3(taci)] ·2 H2O (Pnma, a = 24.314 (5) Å, b = 10.215 (2) Å, c = 7.422 (8) Å, R = 5.8%) and [Co(taci)2(NO3)3]·2H2O (C2/c, a = 22.912 (8) Å, b = 8.942 (2) Å, c = 14.731 (3) Å, β = 128.66 (2)°, R = 4.9%) and the previously investigated [Cr(taci)2]3+ revealed an almost ideal chair conformation in all three molecules." @default.
- W2103308453 created "2016-06-24" @default.
- W2103308453 creator A5041534804 @default.
- W2103308453 creator A5043637507 @default.
- W2103308453 creator A5046564538 @default.
- W2103308453 creator A5047494910 @default.
- W2103308453 creator A5060456428 @default.
- W2103308453 date "1992-11-11" @default.
- W2103308453 modified "2023-09-23" @default.
- W2103308453 title "1,3,5-Triamino-1,3,5-trideoxy-cis-inositol, a New Ligand with a Remarkable Versatility for Metal Ions. Part 2. Safe and efficient ligand preparation and structure of the free ligand and the CoIII complex" @default.
- W2103308453 cites W1974159242 @default.
- W2103308453 cites W1982414593 @default.
- W2103308453 cites W2017404416 @default.
- W2103308453 cites W2028194315 @default.
- W2103308453 cites W2035710815 @default.
- W2103308453 cites W2054721020 @default.
- W2103308453 cites W2065749036 @default.
- W2103308453 cites W2071075852 @default.
- W2103308453 cites W2088970681 @default.
- W2103308453 cites W2092358104 @default.
- W2103308453 cites W2105778666 @default.
- W2103308453 cites W2167684970 @default.
- W2103308453 cites W2950172277 @default.
- W2103308453 doi "https://doi.org/10.1002/hlca.19920750709" @default.
- W2103308453 hasPublicationYear "1992" @default.
- W2103308453 type Work @default.
- W2103308453 sameAs 2103308453 @default.
- W2103308453 citedByCount "41" @default.
- W2103308453 countsByYear W21033084532014 @default.
- W2103308453 countsByYear W21033084532017 @default.
- W2103308453 countsByYear W21033084532018 @default.
- W2103308453 countsByYear W21033084532020 @default.
- W2103308453 countsByYear W21033084532021 @default.
- W2103308453 countsByYear W21033084532022 @default.
- W2103308453 crossrefType "journal-article" @default.
- W2103308453 hasAuthorship W2103308453A5041534804 @default.
- W2103308453 hasAuthorship W2103308453A5043637507 @default.
- W2103308453 hasAuthorship W2103308453A5046564538 @default.
- W2103308453 hasAuthorship W2103308453A5047494910 @default.
- W2103308453 hasAuthorship W2103308453A5060456428 @default.
- W2103308453 hasConcept C106159729 @default.
- W2103308453 hasConcept C111771559 @default.
- W2103308453 hasConcept C116569031 @default.
- W2103308453 hasConcept C134018914 @default.
- W2103308453 hasConcept C155647269 @default.
- W2103308453 hasConcept C161790260 @default.
- W2103308453 hasConcept C162324750 @default.
- W2103308453 hasConcept C170493617 @default.
- W2103308453 hasConcept C178790620 @default.
- W2103308453 hasConcept C185592680 @default.
- W2103308453 hasConcept C21951064 @default.
- W2103308453 hasConcept C2778237882 @default.
- W2103308453 hasConcept C2778541603 @default.
- W2103308453 hasConcept C2778626014 @default.
- W2103308453 hasConcept C2779854550 @default.
- W2103308453 hasConcept C55493867 @default.
- W2103308453 hasConcept C71240020 @default.
- W2103308453 hasConcept C71924100 @default.
- W2103308453 hasConceptScore W2103308453C106159729 @default.
- W2103308453 hasConceptScore W2103308453C111771559 @default.
- W2103308453 hasConceptScore W2103308453C116569031 @default.
- W2103308453 hasConceptScore W2103308453C134018914 @default.
- W2103308453 hasConceptScore W2103308453C155647269 @default.
- W2103308453 hasConceptScore W2103308453C161790260 @default.
- W2103308453 hasConceptScore W2103308453C162324750 @default.
- W2103308453 hasConceptScore W2103308453C170493617 @default.
- W2103308453 hasConceptScore W2103308453C178790620 @default.
- W2103308453 hasConceptScore W2103308453C185592680 @default.
- W2103308453 hasConceptScore W2103308453C21951064 @default.
- W2103308453 hasConceptScore W2103308453C2778237882 @default.
- W2103308453 hasConceptScore W2103308453C2778541603 @default.
- W2103308453 hasConceptScore W2103308453C2778626014 @default.
- W2103308453 hasConceptScore W2103308453C2779854550 @default.
- W2103308453 hasConceptScore W2103308453C55493867 @default.
- W2103308453 hasConceptScore W2103308453C71240020 @default.
- W2103308453 hasConceptScore W2103308453C71924100 @default.
- W2103308453 hasIssue "7" @default.
- W2103308453 hasLocation W21033084531 @default.
- W2103308453 hasOpenAccess W2103308453 @default.
- W2103308453 hasPrimaryLocation W21033084531 @default.
- W2103308453 hasRelatedWork W1507983861 @default.
- W2103308453 hasRelatedWork W1974083897 @default.
- W2103308453 hasRelatedWork W2007414413 @default.
- W2103308453 hasRelatedWork W2016690841 @default.
- W2103308453 hasRelatedWork W2043560322 @default.
- W2103308453 hasRelatedWork W2350870638 @default.
- W2103308453 hasRelatedWork W2365220282 @default.
- W2103308453 hasRelatedWork W2384573759 @default.
- W2103308453 hasRelatedWork W2391746488 @default.
- W2103308453 hasRelatedWork W2395394447 @default.
- W2103308453 hasVolume "75" @default.
- W2103308453 isParatext "false" @default.
- W2103308453 isRetracted "false" @default.
- W2103308453 magId "2103308453" @default.
- W2103308453 workType "article" @default.