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• W2103348605 abstract "The present paper deals with the impact of the addition of β-cyclodextrin on the genesis of cobalt active phases in zirconia-supported catalysts and on their performances in the complete oxidation of formaldehyde. With this aim, a series of cobalt catalysts supported on zirconia (5 wt.%) is prepared by wet impregnation using mixtures of Co(NO3)2 and β-cyclodextrin as precursors. After the impregnation step, the materials are dried and calcined under air at 400 °C. Different ratios of β-cyclodextrin to cobalt have been employed to obtain insight in the role of β-cyclodextrin, i.e. from 0.01 to 1. The ability of β-cyclodextrin to interact with the cobalt salt is investigated in solution by UV–vis spectroscopy, ion conductivity in water and dynamic light scattering measurements. After the impregnation step, the cobalt supported materials are characterized at different stages of the preparation (before and after calcination) by means of conventional techniques including UV–vis spectroscopy, thermogravimetry, N2 adsorption/desorption, X-ray diffraction and temperature-programmed reduction analysis. Characterization results suggest that the carbohydrate ligand bound to the cobalt species retards the decomposition of the cobalt complexes into Co3O4. Finally, these cobalt oxide catalysts prepared from β-cyclodextrin are able to catalyze the oxidation of formaldehyde more efficiently than the control sample. The results are explained in terms of cobalt oxide dispersion and cobalt-support interactions. Indeed, the cobalt oxide particles generated by the thermal decomposition of β-cyclodextrin-Co(II) adducts are on the one hand smaller than those formed with cobalt nitrate alone and on the other hand reducible at lower temperatures, two key factors in the catalytic oxidation reactions." @default.
• W2103348605 created "2016-06-24" @default.
• W2103348605 creator A5002186157 @default.
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• W2103348605 date "2013-07-01" @default.
• W2103348605 modified "2023-10-16" @default.
• W2103348605 title "Effects of β-cyclodextrin introduction to zirconia supported-cobalt oxide catalysts: From molecule-ion associations to complete oxidation of formaldehyde" @default.
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• W2103348605 cites W1963536453 @default.
• W2103348605 cites W1966298701 @default.
• W2103348605 cites W1967206987 @default.
• W2103348605 cites W1974341471 @default.
• W2103348605 cites W1975079795 @default.
• W2103348605 cites W1977548470 @default.
• W2103348605 cites W1977769099 @default.
• W2103348605 cites W1986108248 @default.
• W2103348605 cites W1986305407 @default.
• W2103348605 cites W1990895161 @default.
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• W2103348605 cites W2017014523 @default.
• W2103348605 cites W2026203023 @default.
• W2103348605 cites W2030717200 @default.
• W2103348605 cites W2034488801 @default.
• W2103348605 cites W2039104539 @default.
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• W2103348605 cites W2045454960 @default.
• W2103348605 cites W2048440983 @default.
• W2103348605 cites W2051406158 @default.
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• W2103348605 cites W2055393736 @default.
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• W2103348605 doi "https://doi.org/10.1016/j.apcatb.2013.03.015" @default.
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