Matches in SemOpenAlex for { <https://semopenalex.org/work/W2103365760> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2103365760 endingPage "2035" @default.
- W2103365760 startingPage "2029" @default.
- W2103365760 abstract "Alternating copolymerization of 7-methylenebicyclo[4,1,0]heptane with CO in thf is promoted by catalysts prepared from Pd complexes, PdCl(Me)L (L = chelating diimine or diamine), and NaBARF (BARF = [B{C6H3(CF3)2-3,5}4]−), to produce the polyketone containing enone and 1,2-cyclohexane units. The Pd complexes with Schiff-base type diimines, 2,9-disubstituted 1,10-phenanthroline, and tmen are effective as catalysts to afford the polyketone containing mainly the cis-1,2-disubstituted cyclohexane ring. Polymerization in thf using Schiff-base diimine as the ligand for Pd produces product with a narrow molecular weight distribution (Mw/Mn = 1.10–1.19). The increase in molecular weight during polymerization and polymer growth caused by addition of new monomer indicates living polymerization. The reaction catalyzed by cationic Pd complexes with 2,2′-bipy and phen, prepared from NaBARF and PdCl(Me)L (L = 2,2′-bipy, phen) in CH3CN, produces polymer that contains both trans- and cis-disubstituted cyclohexane rings in almost equal amounts. Heating of the polymer with cis-disubstituted cyclohexane in the presence of sodium o-chlorophenolate induces epimerization of the polymer into thermodynamically more stable polyketones with trans-disubstituted cyclohexane." @default.
- W2103365760 created "2016-06-24" @default.
- W2103365760 creator A5043981429 @default.
- W2103365760 creator A5049600455 @default.
- W2103365760 creator A5088181080 @default.
- W2103365760 date "2003-01-01" @default.
- W2103365760 modified "2023-10-14" @default.
- W2103365760 title "Pd Complex-catalyzed copolymerization of a bicyclic methylenecyclopropane with carbon monoxide to afford a new polyketone" @default.
- W2103365760 cites W1857988173 @default.
- W2103365760 cites W1889685237 @default.
- W2103365760 cites W1964045748 @default.
- W2103365760 cites W1966535524 @default.
- W2103365760 cites W1970028315 @default.
- W2103365760 cites W1971214974 @default.
- W2103365760 cites W1986119632 @default.
- W2103365760 cites W1986327011 @default.
- W2103365760 cites W1987675653 @default.
- W2103365760 cites W1998457424 @default.
- W2103365760 cites W2004182290 @default.
- W2103365760 cites W2006973236 @default.
- W2103365760 cites W2008426816 @default.
- W2103365760 cites W2014793017 @default.
- W2103365760 cites W2015253591 @default.
- W2103365760 cites W2016948478 @default.
- W2103365760 cites W2020424221 @default.
- W2103365760 cites W2025736006 @default.
- W2103365760 cites W2030717370 @default.
- W2103365760 cites W2042729583 @default.
- W2103365760 cites W2043980446 @default.
- W2103365760 cites W2050556181 @default.
- W2103365760 cites W2052863929 @default.
- W2103365760 cites W2053154110 @default.
- W2103365760 cites W2058329520 @default.
- W2103365760 cites W2071207881 @default.
- W2103365760 cites W2074756034 @default.
- W2103365760 cites W2089343610 @default.
- W2103365760 cites W2091928102 @default.
- W2103365760 cites W2165219752 @default.
- W2103365760 cites W2314321524 @default.
- W2103365760 cites W2949111724 @default.
- W2103365760 doi "https://doi.org/10.1039/b211032f" @default.
- W2103365760 hasPublicationYear "2003" @default.
- W2103365760 type Work @default.
- W2103365760 sameAs 2103365760 @default.
- W2103365760 citedByCount "24" @default.
- W2103365760 countsByYear W21033657602014 @default.
- W2103365760 countsByYear W21033657602015 @default.
- W2103365760 countsByYear W21033657602016 @default.
- W2103365760 countsByYear W21033657602020 @default.
- W2103365760 countsByYear W21033657602021 @default.
- W2103365760 countsByYear W21033657602022 @default.
- W2103365760 crossrefType "journal-article" @default.
- W2103365760 hasAuthorship W2103365760A5043981429 @default.
- W2103365760 hasAuthorship W2103365760A5049600455 @default.
- W2103365760 hasAuthorship W2103365760A5088181080 @default.
- W2103365760 hasConcept C155647269 @default.
- W2103365760 hasConcept C161790260 @default.
- W2103365760 hasConcept C166940927 @default.
- W2103365760 hasConcept C178790620 @default.
- W2103365760 hasConcept C183882617 @default.
- W2103365760 hasConcept C185592680 @default.
- W2103365760 hasConcept C188027245 @default.
- W2103365760 hasConcept C2776303508 @default.
- W2103365760 hasConcept C2778237882 @default.
- W2103365760 hasConcept C44228677 @default.
- W2103365760 hasConcept C521977710 @default.
- W2103365760 hasConceptScore W2103365760C155647269 @default.
- W2103365760 hasConceptScore W2103365760C161790260 @default.
- W2103365760 hasConceptScore W2103365760C166940927 @default.
- W2103365760 hasConceptScore W2103365760C178790620 @default.
- W2103365760 hasConceptScore W2103365760C183882617 @default.
- W2103365760 hasConceptScore W2103365760C185592680 @default.
- W2103365760 hasConceptScore W2103365760C188027245 @default.
- W2103365760 hasConceptScore W2103365760C2776303508 @default.
- W2103365760 hasConceptScore W2103365760C2778237882 @default.
- W2103365760 hasConceptScore W2103365760C44228677 @default.
- W2103365760 hasConceptScore W2103365760C521977710 @default.
- W2103365760 hasIssue "10" @default.
- W2103365760 hasLocation W21033657601 @default.
- W2103365760 hasOpenAccess W2103365760 @default.
- W2103365760 hasPrimaryLocation W21033657601 @default.
- W2103365760 hasRelatedWork W1977636304 @default.
- W2103365760 hasRelatedWork W2002193782 @default.
- W2103365760 hasRelatedWork W2034606880 @default.
- W2103365760 hasRelatedWork W2034640367 @default.
- W2103365760 hasRelatedWork W2056403131 @default.
- W2103365760 hasRelatedWork W2094150907 @default.
- W2103365760 hasRelatedWork W2360462188 @default.
- W2103365760 hasRelatedWork W2370081352 @default.
- W2103365760 hasRelatedWork W4232342612 @default.
- W2103365760 hasRelatedWork W52104155 @default.
- W2103365760 isParatext "false" @default.
- W2103365760 isRetracted "false" @default.
- W2103365760 magId "2103365760" @default.
- W2103365760 workType "article" @default.