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• W2103426235 abstract "Abstract The addition of acetonitrile, propionitrile, and phenylacetonitrile to tetramesityldisilene (Mes 2 SiSiMes 2 ) was examined. In general, 1,2,3‐azadisiletines and the tautomeric enamines were formed, although a ketenimine was formed as the major product in the addition of phenylacetonitrile to the disilene. In the presence of LiCl, the mode of addition changed for both acetonitrile and propionitrile: insertion into the α‐CH bond of acetonitrile and/or formation of the formal HCN adduct was observed. Preliminary investigations of the reactivity of the nitrile adducts are also reported. A comparison between the reactivity of nitriles with Mes 2 SiSiMes 2 and the Si(100)‐2×1 surface was made both in terms of the types of adducts formed and their reactivity. Some insights into the surface chemistry are offered." @default.
• W2103426235 created "2016-06-24" @default.
• W2103426235 creator A5006704551 @default.
• W2103426235 creator A5038664561 @default.
• W2103426235 date "2014-12-18" @default.
• W2103426235 modified "2023-10-18" @default.
• W2103426235 title "The Addition of Nitriles to Tetramesityldisilene: A Comparison of the Reactivity between Surface and Molecular Disilenes" @default.
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• W2103426235 doi "https://doi.org/10.1002/chem.201405780" @default.
• W2103426235 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25524591" @default.
• W2103426235 hasPublicationYear "2014" @default.
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