Matches in SemOpenAlex for { <https://semopenalex.org/work/W2103451275> ?p ?o ?g. }
- W2103451275 endingPage "682" @default.
- W2103451275 startingPage "677" @default.
- W2103451275 abstract "Novel thiosemicarbazonato complexes of gold(III) have been prepared from reactions of [Au(damp-C1,N)Cl2 (damp- = 2-(N,N-dimethylaminomethyl)phenyl) or [NBu4][AuCl4] with 2-pyridineformamide thiosemicarbazones (HL). The thiosemicarbazones deprotonate and coordinate as mononegative, tridentate NNS ligands to gold to give [Au(Hdamp-C1)(L)]Cl2 or [AuCl(L)]Cl complexes. The organometallic damp− ligand is protonated during the reactions and the Au–N bond is cleaved. The [AuCl(L)]+ cations represent the first gold(III) complexes with thiourea derivatives which are not stabilised by an additional organometallic ligand. Reactions of [NBu4][AuX4] (X = Cl, Br) with diphenylthiocarbazone (dithizone) result in reduction of the metal and the formation of gold(I) complexes of the composition [AuX(SCN4-3,4-Ph2)] where SCN4-3,4-Ph2 is 3,4-diphenyltetrazole thione which is formed from cyclisation of dithizone." @default.
- W2103451275 created "2016-06-24" @default.
- W2103451275 creator A5003716046 @default.
- W2103451275 creator A5032467198 @default.
- W2103451275 creator A5077569418 @default.
- W2103451275 date "2004-01-01" @default.
- W2103451275 modified "2023-10-11" @default.
- W2103451275 title "Stable gold(<scp>iii</scp>) complexes with thiosemicarbazone derivatives" @default.
- W2103451275 cites W1967506930 @default.
- W2103451275 cites W1971437863 @default.
- W2103451275 cites W1972526354 @default.
- W2103451275 cites W1977085692 @default.
- W2103451275 cites W1981356976 @default.
- W2103451275 cites W1982810483 @default.
- W2103451275 cites W1984611145 @default.
- W2103451275 cites W1989900124 @default.
- W2103451275 cites W1991514268 @default.
- W2103451275 cites W2002593074 @default.
- W2103451275 cites W2002814931 @default.
- W2103451275 cites W2004977981 @default.
- W2103451275 cites W2007159428 @default.
- W2103451275 cites W2010050160 @default.
- W2103451275 cites W2011643516 @default.
- W2103451275 cites W2012521954 @default.
- W2103451275 cites W2016740514 @default.
- W2103451275 cites W2022432183 @default.
- W2103451275 cites W2023749745 @default.
- W2103451275 cites W2027337233 @default.
- W2103451275 cites W2030506493 @default.
- W2103451275 cites W2030559842 @default.
- W2103451275 cites W2036039162 @default.
- W2103451275 cites W2042756758 @default.
- W2103451275 cites W2053429131 @default.
- W2103451275 cites W2053601675 @default.
- W2103451275 cites W2056789175 @default.
- W2103451275 cites W2057387900 @default.
- W2103451275 cites W2059020082 @default.
- W2103451275 cites W2059882063 @default.
- W2103451275 cites W2063815637 @default.
- W2103451275 cites W2064163763 @default.
- W2103451275 cites W2066493085 @default.
- W2103451275 cites W2067315209 @default.
- W2103451275 cites W2087216877 @default.
- W2103451275 cites W2089119711 @default.
- W2103451275 cites W2159248510 @default.
- W2103451275 cites W2160320728 @default.
- W2103451275 cites W2236469781 @default.
- W2103451275 cites W2315229605 @default.
- W2103451275 cites W243569686 @default.
- W2103451275 cites W279122950 @default.
- W2103451275 cites W2886589918 @default.
- W2103451275 doi "https://doi.org/10.1039/b312978k" @default.
- W2103451275 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15252533" @default.
- W2103451275 hasPublicationYear "2004" @default.
- W2103451275 type Work @default.
- W2103451275 sameAs 2103451275 @default.
- W2103451275 citedByCount "58" @default.
- W2103451275 countsByYear W21034512752012 @default.
- W2103451275 countsByYear W21034512752013 @default.
- W2103451275 countsByYear W21034512752014 @default.
- W2103451275 countsByYear W21034512752015 @default.
- W2103451275 countsByYear W21034512752017 @default.
- W2103451275 countsByYear W21034512752018 @default.
- W2103451275 countsByYear W21034512752019 @default.
- W2103451275 countsByYear W21034512752020 @default.
- W2103451275 countsByYear W21034512752021 @default.
- W2103451275 countsByYear W21034512752022 @default.
- W2103451275 countsByYear W21034512752023 @default.
- W2103451275 crossrefType "journal-article" @default.
- W2103451275 hasAuthorship W2103451275A5003716046 @default.
- W2103451275 hasAuthorship W2103451275A5032467198 @default.
- W2103451275 hasAuthorship W2103451275A5077569418 @default.
- W2103451275 hasConcept C115624301 @default.
- W2103451275 hasConcept C116569031 @default.
- W2103451275 hasConcept C145148216 @default.
- W2103451275 hasConcept C155647269 @default.
- W2103451275 hasConcept C170493617 @default.
- W2103451275 hasConcept C178790620 @default.
- W2103451275 hasConcept C179104552 @default.
- W2103451275 hasConcept C185592680 @default.
- W2103451275 hasConcept C2779665717 @default.
- W2103451275 hasConcept C2780538656 @default.
- W2103451275 hasConcept C30095370 @default.
- W2103451275 hasConcept C514695523 @default.
- W2103451275 hasConcept C544153396 @default.
- W2103451275 hasConcept C55493867 @default.
- W2103451275 hasConcept C71240020 @default.
- W2103451275 hasConcept C8010536 @default.
- W2103451275 hasConcept C83591994 @default.
- W2103451275 hasConceptScore W2103451275C115624301 @default.
- W2103451275 hasConceptScore W2103451275C116569031 @default.
- W2103451275 hasConceptScore W2103451275C145148216 @default.
- W2103451275 hasConceptScore W2103451275C155647269 @default.
- W2103451275 hasConceptScore W2103451275C170493617 @default.
- W2103451275 hasConceptScore W2103451275C178790620 @default.
- W2103451275 hasConceptScore W2103451275C179104552 @default.
- W2103451275 hasConceptScore W2103451275C185592680 @default.
- W2103451275 hasConceptScore W2103451275C2779665717 @default.