Matches in SemOpenAlex for { <https://semopenalex.org/work/W2103452022> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2103452022 endingPage "4932" @default.
- W2103452022 startingPage "4922" @default.
- W2103452022 abstract "This research was focused on the design and execution of new synthetic routes to low-temperature-curable poly(silarylene–siloxane)polyimides. The synthesis of individual oligoimide and silarylene–siloxane blocks was followed by hydrosilylation polymerization to produce crosslinked copolymers. The silarylene–siloxane and polyimide blocks were structurally characterized by IR and 1H NMR spectroscopy and size exclusion chromatography. The high-temperature resistance of the copolymers was evaluated through the measurement of heat distortion temperatures (THD's) via thermomechanical analysis and by the determination of the weight loss at elevated temperatures via thermogravimetric analysis. Glass-transition temperatures (Tg's) of the silarylene–siloxane segments were measured by differential scanning calorimetry. Hydrosilylation curing was conducted at 60 °C in the presence of chloroplatinic acid (H2PtCl6). The copolymers displayed both high-temperature resistance and low-temperature flexibility. We observed Tg of the silarylene–siloxane segment as low as −77 °C and THD of the polyimide segment as high as 323 °C. The influence of various oligoimide molecular weights on the properties of copolymers containing the same silarylene–siloxane was examined. The effect of various silarylene–siloxane molecular weights on the properties of copolymers containing the same oligoimide was also examined. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 4922–4932, 2005" @default.
- W2103452022 created "2016-06-24" @default.
- W2103452022 creator A5034793267 @default.
- W2103452022 creator A5077748984 @default.
- W2103452022 creator A5089089347 @default.
- W2103452022 date "2005-01-01" @default.
- W2103452022 modified "2023-09-27" @default.
- W2103452022 title "Poly(silarylene-siloxane)polyimides from allyl-terminated oligoimides and hydride-functional silarylene-siloxanes via hydrosilylation polymerization" @default.
- W2103452022 cites W1436293430 @default.
- W2103452022 cites W1771410 @default.
- W2103452022 cites W1992584377 @default.
- W2103452022 cites W2000638815 @default.
- W2103452022 cites W2013478392 @default.
- W2103452022 cites W2020879108 @default.
- W2103452022 cites W2028280638 @default.
- W2103452022 cites W2073294414 @default.
- W2103452022 cites W2077020196 @default.
- W2103452022 cites W2100258519 @default.
- W2103452022 cites W2103503290 @default.
- W2103452022 cites W2117390553 @default.
- W2103452022 cites W2129680767 @default.
- W2103452022 cites W2621620900 @default.
- W2103452022 doi "https://doi.org/10.1002/pola.20962" @default.
- W2103452022 hasPublicationYear "2005" @default.
- W2103452022 type Work @default.
- W2103452022 sameAs 2103452022 @default.
- W2103452022 citedByCount "10" @default.
- W2103452022 countsByYear W21034520222012 @default.
- W2103452022 countsByYear W21034520222013 @default.
- W2103452022 countsByYear W21034520222014 @default.
- W2103452022 countsByYear W21034520222020 @default.
- W2103452022 crossrefType "journal-article" @default.
- W2103452022 hasAuthorship W2103452022A5034793267 @default.
- W2103452022 hasAuthorship W2103452022A5077748984 @default.
- W2103452022 hasAuthorship W2103452022A5089089347 @default.
- W2103452022 hasConcept C121332964 @default.
- W2103452022 hasConcept C122865956 @default.
- W2103452022 hasConcept C127413603 @default.
- W2103452022 hasConcept C132976073 @default.
- W2103452022 hasConcept C15920480 @default.
- W2103452022 hasConcept C159985019 @default.
- W2103452022 hasConcept C161790260 @default.
- W2103452022 hasConcept C178790620 @default.
- W2103452022 hasConcept C185592680 @default.
- W2103452022 hasConcept C188027245 @default.
- W2103452022 hasConcept C192562407 @default.
- W2103452022 hasConcept C2776139660 @default.
- W2103452022 hasConcept C2778421718 @default.
- W2103452022 hasConcept C2779227376 @default.
- W2103452022 hasConcept C2780965675 @default.
- W2103452022 hasConcept C39519442 @default.
- W2103452022 hasConcept C42360764 @default.
- W2103452022 hasConcept C44228677 @default.
- W2103452022 hasConcept C521977710 @default.
- W2103452022 hasConcept C53033327 @default.
- W2103452022 hasConcept C60100273 @default.
- W2103452022 hasConcept C97355855 @default.
- W2103452022 hasConceptScore W2103452022C121332964 @default.
- W2103452022 hasConceptScore W2103452022C122865956 @default.
- W2103452022 hasConceptScore W2103452022C127413603 @default.
- W2103452022 hasConceptScore W2103452022C132976073 @default.
- W2103452022 hasConceptScore W2103452022C15920480 @default.
- W2103452022 hasConceptScore W2103452022C159985019 @default.
- W2103452022 hasConceptScore W2103452022C161790260 @default.
- W2103452022 hasConceptScore W2103452022C178790620 @default.
- W2103452022 hasConceptScore W2103452022C185592680 @default.
- W2103452022 hasConceptScore W2103452022C188027245 @default.
- W2103452022 hasConceptScore W2103452022C192562407 @default.
- W2103452022 hasConceptScore W2103452022C2776139660 @default.
- W2103452022 hasConceptScore W2103452022C2778421718 @default.
- W2103452022 hasConceptScore W2103452022C2779227376 @default.
- W2103452022 hasConceptScore W2103452022C2780965675 @default.
- W2103452022 hasConceptScore W2103452022C39519442 @default.
- W2103452022 hasConceptScore W2103452022C42360764 @default.
- W2103452022 hasConceptScore W2103452022C44228677 @default.
- W2103452022 hasConceptScore W2103452022C521977710 @default.
- W2103452022 hasConceptScore W2103452022C53033327 @default.
- W2103452022 hasConceptScore W2103452022C60100273 @default.
- W2103452022 hasConceptScore W2103452022C97355855 @default.
- W2103452022 hasIssue "20" @default.
- W2103452022 hasLocation W21034520221 @default.
- W2103452022 hasOpenAccess W2103452022 @default.
- W2103452022 hasPrimaryLocation W21034520221 @default.
- W2103452022 hasRelatedWork W169472305 @default.
- W2103452022 hasRelatedWork W1991029910 @default.
- W2103452022 hasRelatedWork W2022843117 @default.
- W2103452022 hasRelatedWork W2040513760 @default.
- W2103452022 hasRelatedWork W2103452022 @default.
- W2103452022 hasRelatedWork W2113056904 @default.
- W2103452022 hasRelatedWork W2148043506 @default.
- W2103452022 hasRelatedWork W2170159502 @default.
- W2103452022 hasRelatedWork W2350328062 @default.
- W2103452022 hasRelatedWork W3206252680 @default.
- W2103452022 hasVolume "43" @default.
- W2103452022 isParatext "false" @default.
- W2103452022 isRetracted "false" @default.
- W2103452022 magId "2103452022" @default.
- W2103452022 workType "article" @default.