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• W2103453757 abstract "Unprecedented supramolecular stacks of highly reduced geodesic π-systems were prepared by the reduction of the derivatized fullerenes Me5C60H and Ph5C60H and corannulene with lithium metal (R5C605-/Cor4-/9Li+). The host−guest assemblies form because of the enhanced electrostatic interactions between the lithium cations and the anionic moieties, in addition to the structural compatibility between the curved hydrocarbons. The high stability of these new supramolecular assemblies (heterodimers) enables the introduction of another organization motif to the system. This is achieved by using tethered corannulenes as host molecules, which leads to the formation of tethered bis-heterodimers ((Me5C605-/Cor4-)2(CH2)8/18Li+)." @default.
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• W2103453757 date "2005-06-09" @default.
• W2103453757 modified "2023-10-16" @default.
• W2103453757 title "Ball-and-Socket Stacking of Supercharged Geodesic Polyarenes: Bonding by Interstitial Lithium Ions" @default.
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• W2103453757 doi "https://doi.org/10.1021/ja0515102" @default.
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