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- W2103454064 abstract "Substituted epichlorohydrins 3 or 6 are obtained from α-bromo or α-chlorocarbonyl compounds (1 or 4) and chloro or iodomethyllithium, respectively. Starting from α-bromocarbonyl compounds 1 or acyclic α-chloro ketones the reaction takes place with total diastereoselectivity. Treatment of epichlorohydrins 3 or 6 with lithium iodide affords the same substituted allyl alcohols 7 in a regioselective manner. A mechanism to explain this transformation is proposed. Regioisomeric allyl alcohols 11 are prepared by reaction of epichlorohydrins 6 with lithium powder." @default.
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- W2103454064 date "1995-05-01" @default.
- W2103454064 modified "2023-09-27" @default.
- W2103454064 title "Highly diastereoselective synthesis of substituted epichlorohydrins and regioselective preparation of allyl alcohols using chloro or iodomethyllithium" @default.
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- W2103454064 doi "https://doi.org/10.1016/0040-4020(95)90943-q" @default.
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