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• W2103500698 abstract "Abstract A direct synthesis of polysubstituted olefins via construction of CC bonds, which involves the direct dehydrative coupling of alcohols or alkenes with alcohols, was realized using a series of alkanesulfonic acid group‐functionalized ionic liquids (SO 3 H‐functionlization ILs) without additives. The metal‐free and recyclable catalyst system avoided the disposal and neutralization of acidic catalysts after reaction and tolerated a broad range of substrates, including benzylic, allyl, propargylic, aliphatic and aromatic or aliphatic olefins. Additionally, the catalytic system was suitable for a gram‐scale preparation. Preliminary mechanistic studies indicated that the CH bond cleavage in this reaction might be involved in the rate‐determining step. magnified image" @default.
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• W2103500698 date "2014-06-25" @default.
• W2103500698 modified "2023-10-10" @default.
• W2103500698 title "Metal‐Free and Recyclable Route to Synthesize Polysubstituted Olefins <i>via</i> CC Bond Construction from Direct Dehydrative Coupling of Alcohols or Alkenes with Alcohols Catalyzed by Sulfonic Acid‐Functionalized Ionic Liquids" @default.
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• W2103500698 doi "https://doi.org/10.1002/adsc.201301150" @default.
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