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- W2103555692 abstract "Solution studies of the interaction of Me2Sn(IV) 2+ and Me3Sn(IV) + with catecholamines (L- dopa and L-tyrosine) in aqueous medium ( µ=0.05 ,0.10 and 0.15 M NaNO3 and Temperature = 20±1°C, 30±1°C and 40±1°C) are performed. The concentrationdistribution of the various complex species in solution is evaluated as a function of pH.SCOGS computer programme is used for computational analysis. The complex species formed are water soluble in the pH range 2.8-10.5. In all of the studied systems, no polymeric species are detected in the experimental range. Thermodynamic stability constants along with thermodynamic parameters i.e. standard free energy change (∆Go) enthalpy change (∆Ho) and entropy change(∆So) are calculated for all the systems. It is observed that L-dopa interact more strongly than that of L- tyrosine with both Me2Sn(IV) 2+ and Me3Sn(IV) + cations. Whereas, on the basis of metals it is concluded that complexes of Me2Sn(IV) 2+ are thermodynamically more stable than those of Me3Sn(IV) + complexes. Me2Sn(IV) 2+ and Me3Sn(IV) + stands for" @default.
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- W2103555692 date "2015-01-01" @default.
- W2103555692 modified "2023-09-26" @default.
- W2103555692 title "Interaction Of Me2Sn (IV) 2+ And Me3Sn (IV) + Cations With Catecholamines In Aqueous Media" @default.
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- W2103555692 doi "https://doi.org/10.6084/m9.figshare.1341998.v1" @default.
- W2103555692 hasPublicationYear "2015" @default.
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