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- W2103596051 abstract "Using surface x-ray diffraction we have investigated growth and structure of Fe deposited on Pd(001) at room temperature. Up to about 4.2 ML, the maximum film thickness studied, Fe grows in layer-by-layer mode without sizable intermixing with Pd. Up to 1.5 ML coverage the Fe film adopts a fct-structure followed by a transition to a bct-structure at higher film thickness. The top Pd interlayer spacing, which in the case of uncovered Pd(001) is expanded by up to $6.5ifmmodepmelsetextpmfi{}2.0%$ relative to the bulk due to adsorbed hydrogen relaxes to $0ifmmodepmelsetextpmfi{}2%$ upon adsorption of 0.6 ML Fe, possibly due to displacement into subsurface sites. Mild annealing $(400phantom{rule{0.3em}{0ex}}mathrm{K})$ of a 1 ML $mathrm{Fe}∕mathrm{Pd}(001)$ sample induces surface alloying leading to a disordered two layer thick fct-${mathrm{Fe}}_{50}{mathrm{Pd}}_{50}$-alloy." @default.
- W2103596051 created "2016-06-24" @default.
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- W2103596051 date "2006-06-27" @default.
- W2103596051 modified "2023-10-17" @default.
- W2103596051 title "No alloying in Fe deposited on Pd(001) at room temperature" @default.
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- W2103596051 doi "https://doi.org/10.1103/physrevb.73.245432" @default.
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