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- W2103646416 endingPage "2628" @default.
- W2103646416 startingPage "2618" @default.
- W2103646416 abstract "A mono- and a 1,3-bis-phosphite arene ligand based on 2,2′-biphenol have been synthesized in order to study the synthesis of the corresponding palladium(II) complexes starting from different Pd precursors. Novel bis-phosphite palladium complex 1 [PdCl2(L)2] (L = dibenzo[d,f][1,3,2]dioxaphosphepin, 6-phenoxy), C,P-chelate bonded monophosphite palladium complex 2 [Pd(κ2-L)(μ-Cl)]2, and PCP-pincer palladium complex 3 have been prepared from these ligands in promising to excellent yields (50–95%). Additionally, complexes 1 and 3 have been characterized by X-ray crystal structure determinations. The application of 2,6-bis-phosphite pincer palladium(II) complex 3 in C–P cross-coupling between diphenylphosphine-borane and a wide range of various aryl iodides under very mild conditions is reported. Kinetic investigations indicate that 3 merely acts as a pre-catalyst and that Pd nanoparticles are the actual catalytically active species." @default.
- W2103646416 created "2016-06-24" @default.
- W2103646416 creator A5037093217 @default.
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- W2103646416 creator A5050300271 @default.
- W2103646416 creator A5070010505 @default.
- W2103646416 creator A5089521767 @default.
- W2103646416 date "2010-11-01" @default.
- W2103646416 modified "2023-10-16" @default.
- W2103646416 title "Novel phosphite palladium complexes and their application in C–P cross-coupling reactions" @default.
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