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- W2103663659 abstract "A kinetic study of the complex formation between chlororuthenate(II) species and 1,1-difluoroethylene and vinyl fluoride under mild conditions in aqueous hydrochloric acid solution is described; a two step process involving an initial dissociation of a chloride ligand seems likely for these systems but a detailed discussion is limited by lack of information on the equilibria between chlororuthenate(II) species in solution. The fluoroolefins are not homogeneously catalytically hydrogenated at Ru II due to a competing catalytic hydration process which converts 1,1-difluoroethylene to acetic acid and vinyl fluoride to acetaldehyde. Similarities between the mechanisms of catalytic hydration and hydrogenation are discussed." @default.
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- W2103663659 date "1969-01-01" @default.
- W2103663659 modified "2023-09-26" @default.
- W2103663659 title "Formation and catalytic properties of some ruthenium(II) halogeno-olefin complexes in solution" @default.
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- W2103663659 doi "https://doi.org/10.1016/s0020-1693(00)92553-2" @default.
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