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• W2103670125 abstract "The carbon-sulphur bond in aliphatic diphenyldithio-acetals, α-carbonyldiphenyldithioacetals and α-carbonylketene dimethyldithioacetals can be cleaved cathodlcally on mercury (Hg) or glassy carbon (GC) electrodes.In the presence of tetra-butylammoniumhydrogensulphate (TBAHSO4) as a proton donor one thio-phenyl- respectively thiomethyl group is substituted by hydrogen to provide the corresponding phenylthioethers (phenylthiomethyl) ketones or methylthiovinylketones in very good yields. At a Hg cathode the electroreduction of α-carbonyldiphenyldi-thioacetals is self-catalyzed." @default.
• W2103670125 created "2016-06-24" @default.
• W2103670125 creator A5043542116 @default.
• W2103670125 creator A5083993418 @default.
• W2103670125 date "1987-01-01" @default.
• W2103670125 modified "2023-09-23" @default.
• W2103670125 title "Electroreductive cleavage of carbon-sulphur bonds in dithioacetals" @default.
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• W2103670125 doi "https://doi.org/10.1016/s0040-4020(01)81653-7" @default.
• W2103670125 hasPublicationYear "1987" @default.
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