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- W2103695234 abstract "Abstract The improved synthesis of the antitumor compound (+)‐tedanolide is described through an aldol coupling of bis‐ketone 7 . This modification shortens the synthetic steps in the endgame and provides rapid access to this biologically important natural product. Additionally, it serves as a probe in order to unravel the conformational effects that impede or enable its successful synthesis. Having this way access to des‐epoxy‐tedanolide, its biological characterization surprisingly unravelled the mode of action to resemble candidaspongiolide rather than deoxytedanolide." @default.
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- W2103695234 date "2012-03-05" @default.
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- W2103695234 title "An Improved Route to (+)‐Tedanolide and Analysis of Its Subtle Effects Controlling Conformation and Biological Behaviour" @default.
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- W2103695234 doi "https://doi.org/10.1002/chem.201103038" @default.
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