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• W2103709892 abstract "Reactions of imino-pyridyl ligands, (2-pyridyl-2-thiophenemethyl)imine (L1) and (2-pyridyl-2-thiopheneethyl)imine (L2) with NiBr2(DME) gave the corresponding complexes [Ni(L1)Br2] (1) and [Ni(L2)Br2] (2) in good yields. Treatment of 1 and 2 with one equivalent of 2-hydroxythiophenol resulted in the displacement of the bromide ligands to form the nickel(II) thiolato complexes 3 and 4. Molecular structure of 3 confirmed that L1 and L2 bind to the nickel atom in a bidentate fashion. Complexes 1–4 catalyzed the Heck coupling reaction of iodobenzene and bromobenzene with methyl acrylate." @default.
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• W2103709892 date "2012-08-01" @default.
• W2103709892 modified "2023-09-27" @default.
• W2103709892 title "New imino-pyridyl nickel(II) complexes: Synthesis, molecular structures and application as Heck coupling catalysts" @default.
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• W2103709892 doi "https://doi.org/10.1016/j.ica.2012.04.037" @default.
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