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• W2103730899 abstract "The development of selective catalytic methods to oxidize organic substrates is often a nontrivial exercise. Few classes of organic reactions are as mechanistically complex and often as difficult to control and render selective as metal catalyzed oxidations [1, 2]. The inherent kinetic behavior of oxidants and substrates as well as other factors can give rise to formidable obstacles in this area. A fact of more than passing significance in all organic oxidation processes, and one often overlooked in research and development efforts is that both the reactants (substrates) and the products are thermodynamically unstable with respect to further oxidation to CO2 and H2O. Within this inherent limitation, it is the systematic control of a number of kinetic processes that dictate the observed chemistry. The title subject is of very recent vintage and as a consequence most of the literature cited in this chapter is quite recent. In order to review this subject properly, the fundamental and pertinent chemical and physical features of both hydrogen peroxide reactions and polyoxometalates must be presented. Before we turn to an elaboration of these subjects in the appropriately designated sections of the chapter below, we first discuss several points relevant to the development of oxidation and/or catalytic processes in general." @default.
• W2103730899 created "2016-06-24" @default.
• W2103730899 creator A5019150257 @default.
• W2103730899 date "1992-01-01" @default.
• W2103730899 modified "2023-10-16" @default.
• W2103730899 title "The Use of Polyoxometalates in Reactions with Hydrogen Peroxide" @default.
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• W2103730899 doi "https://doi.org/10.1007/978-94-017-0984-2_8" @default.
• W2103730899 hasPublicationYear "1992" @default.
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