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• W2103770816 abstract "Catalyst tuning by changing ligands is a well-established protocol in transition-metal chemistry. N-Heterocyclic carbenes (NHCs) and tertiary phosphines (R3P) are the ubiquitous ligand actors. Here we demonstrate that the relative σ-donor/π-acceptor ability of the NHC ligand itself can be influenced by a simple substituent-controlled conformational change, thereby directly impacting the reactivity of the transition-metal complex." @default.
• W2103770816 created "2016-06-24" @default.
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• W2103770816 date "2009-04-27" @default.
• W2103770816 modified "2023-09-27" @default.
• W2103770816 title "N-Heterocyclic Carbene-Functionalized Ruthenium Phosphinidenes: What a Difference a Twist Makes" @default.
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• W2103770816 doi "https://doi.org/10.1021/ja901540h" @default.
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• W2103770816 hasPublicationYear "2009" @default.
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