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- W2103784105 abstract "Ionothermal reaction of DyCl3·6H2O with 1,4-benzenedicarboxylic acid (H2BDC) in 1-ethyl-3-methylimidazolium bromide (EMIM-Br) leads to a novel compound {(EMIM)[Dy3(BDC)5]}n (1). Compound 1 consists of the extraframework charge-balancing cation [EMIM]+ and the [Dy3(BDC)5]nn− anionic framework with hex topology. The 3D [Dy3(BDC)5]nn− framework is constructed from the 1D rod-shaped Dy–carboxylate secondary building unit wherein the 6-, 8-, and 9-coordinated Dy(III) ions are alternately arranged. Detailed static and dynamic magnetic analysis of 1 revealed that 1 exhibits a slow magnetic relaxation behavior typical of single-molecule magnets (SMMs). Compound 1 displays an anisotropic energy barrier of 39.3 K and a pre-exponential factor τ0 of 2.6 × 10−10 s in the presence of a direct-current field of 2 kOe." @default.
- W2103784105 created "2016-06-24" @default.
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- W2103784105 date "2014-01-01" @default.
- W2103784105 modified "2023-10-16" @default.
- W2103784105 title "Ionothermal synthesis of a 3D dysprosium–1,4-benzenedicarboxylate framework based on the 1D rod-shaped dysprosium–carboxylate building blocks exhibiting slow magnetization relaxation" @default.
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- W2103784105 doi "https://doi.org/10.1039/c3ce41624k" @default.
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