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- W2103929083 abstract "The configurations at the ring junctions of the tricyclic pyrans (1RS,2SR,6RS,7RS,8RS)-6,7-dihydroxy-3-oxatricyclo[6.6.0.0 2,7 ]tetradec-1-yl acetate, C 15 H 24 O 5 , and (1RS,2RS,6SR,7SR,8RS)-6,7-dihydroxy-3-oxatricyclo[6.6.0.0 2,7 ]tetradec-1-yl acetate monohydrate, C 15 H 24 O 5 .H 2 O, indicate that, in the reactions leading to these compounds, hydroxylation always takes place on the less hindered side of the substrate, and that the heterocycle exerts greater steric hindrance than the carbocycle. The structures and conformations of the two stereoisomers and their hydrogen bonding are discussed." @default.
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- W2103929083 date "2010-08-12" @default.
- W2103929083 modified "2023-09-26" @default.
- W2103929083 title "ChemInform Abstract: Stereochemistry of Hydroxylation Reactions on Polycyclic Pyrans." @default.
- W2103929083 cites W2950934088 @default.
- W2103929083 doi "https://doi.org/10.1002/chin.199604041" @default.
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