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- W2103956285 abstract "Paracyclophene based monomers can be polymerized in a living fashion using the alkylidene initiator Mo(NAr)(CHCMe2Ph)(OCMe(CF3)2)2. The cis-specific nature of the polymerization is critical, since small amounts of trans olefin in the backbone renders the material insoluble. These polymers have complex photophysical behavior, probably a consequence of the close proximity of chromophores along the polymer backbone. Polymerization of 9-(tert-butyldimethylsilyloxy)-[2.2]-paracyclophan-1-ene produces a new precursor material which furnishes PPV under remarkably mild conditions." @default.
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- W2103956285 date "1995-06-01" @default.
- W2103956285 modified "2023-10-11" @default.
- W2103956285 title "Living and stereoselective polymerization of [2.2]-paracyclophan-2-ENE derivatives" @default.
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- W2103956285 doi "https://doi.org/10.1002/masy.19950950116" @default.
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