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- W2103993171 abstract "The first and second overtone absorption of pure carbon monoxide was measured at supercritical temperatures between 293 K and 500 K in an extended pressure range up to 2.8 kbar. The near infrared bandshape, almost up to the critical density, is adequately represented by summing up over individual rotation-vibration lines with half-widths proportional to density. Band maximum positions and vibrational intensities between gaseous and liquid-like states are reported and discussed. The molar integrated absorptivity is independent of temperature and, in the first overtone, varies by less than 2% with density which enables direct and precise measurements of CO concentrations in fluid phase equilibria and reactions via high-pressure near infrared Spectroscopy." @default.
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- W2103993171 date "1985-05-01" @default.
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- W2103993171 title "First and Second Overtone Absorption of Pure Carbon Monoxide to High Pressures and Temperatures" @default.
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- W2103993171 doi "https://doi.org/10.1002/bbpc.19850890516" @default.
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