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- W2104021836 abstract "Carbon paste ion-selective electrodes based on complexes of copper with the macrocyclic 3,4,10,11-tetraphenyl-1,2,5,8,9,12,13-octaaza-cyclotetra-deca-7,14-dithizone-2,4,9,11-tetraene, L 1 , and benzilbisthiosemicarbazone, L 2 , were constructed for copper determination. The calibration graphs were linear for a wide concentration range (1×10 −5 –1×10 −2 mol l −1 ). The limits of detection for Cu–L 1 (1:1) and (1:2) complexes were p Cu=5.2 and 4.8, whereas for Cu–L 2 (1:1) and (1:2) complexes were p Cu=5.6 and 4.8, respectively. Selectivity coefficients were tabulated. The response times for these electrodes were fast and stable potentials were obtained within 2–18 s for concentrations higher than 10 −4 mol l −1 . The electrodes were applied to potentiometric titrations of humic acids with copper(II) and show promise for the determination of complexation characteristic of these compounds." @default.
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- W2104021836 date "1999-04-01" @default.
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- W2104021836 title "Copper potentiometric sensors based on copper complexes containing thiohydrazone and thiosemicarbazone ligands" @default.
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- W2104021836 doi "https://doi.org/10.1016/s0003-2670(98)00840-x" @default.
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