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- W2104215087 abstract "Nucleophile Austauschreaktionen von Malononitril am arylsubstituierten Dreiecksäureamidiniumkation 5, am 1,2-Dithioquadratsäurebis(dimethylamid) (13) oder am Krokonsäure-dimethylester (20) führen zu den entsprechenden Dicyanmethylenderivaten 6, 14 bzw. 21, die durch anschließende Sulfhydrolyse zu den neuen schwefelhaltigen, delokalisierten “Pseudooxokohlenstoff” Anionen 8, 15 bzw. 22 reagieren. Alkylierungsreaktionen an diesen Anionen und ihre spektroskopischen Daten werden mitgeteilt. Polycarbonyl Compounds, XXIX. — Sulfur Containing Dicyanomethylene-“Pseudooxocarbon” Anions Nucleophilic replacement reactions of malononitrile at the aryl-substituted deltic acid amidinium cation 5, at 1,2-dithiosquaric acid bis(dimethylamide) (13), or at croconic acid dimethyl ester (20) lead to the corresponding dicyanomethylene derivatives 6, 14, or 21, respectively, which on subsequent sulfhydrolysis yield the novel sulfur containing delocalized “pseudooxocarbon” anions 8, 15, or 22, respectively. Alkylation reactions of these anions as well as spectroscopic data are reported." @default.
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- W2104215087 date "1980-09-26" @default.
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- W2104215087 title "Polycarbonylverbindungen, XXIX. Schwefelhaltige Dicyanmethylen-“Pseudooxokohlenstoff”-Anionen" @default.
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- W2104215087 doi "https://doi.org/10.1002/jlac.198019800909" @default.
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