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• W2104328384 abstract "Thermal decomposition of magnesium borohydride, Mg(BH4)2, in the solid state was studied by a combination of PCT, TGA/MS and NMR spectroscopy. Dehydrogenation of Mg(BH4)2 at 200 °C en vacuo results in the highly selective formation of magnesium triborane, Mg(B3H8)2. This process is reversible at 250 °C under 120 atm H2. Dehydrogenation at higher temperature, >300 °C under a constant argon flow of 1 atm, produces a complex mixture of polyborane species. A borohydride condensation mechanism involving metal hydride formation is proposed." @default.
• W2104328384 created "2016-06-24" @default.
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• W2104328384 date "2011-01-01" @default.
• W2104328384 modified "2023-09-30" @default.
• W2104328384 title "Reversible dehydrogenation of magnesium borohydride to magnesium triborane in the solid state under moderate conditions" @default.
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• W2104328384 doi "https://doi.org/10.1039/c0cc03461d" @default.
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